S.T.A.L.K.E.R.
All three base games. So many mods.
The zone feels vast, lived in, dangerous.
The ai is dynamic, moving through an area once you mind find a group of friendlies engaged in a firefight with a powerful psychic mutant, and other time find an eerily peaceful vista.
It's not a power fantasy. On harder difficulties you're always on edge when you're exploring even with end game gear. A single bullet from a sniper or a random pack of wild dogs can easily end your run.
Highly recommended of you've never experienced it before.