Time measurements like heat, mass, length etc are arbitrary units. It is just that they are the oldest.
The Sumerians gave us our time standards and they loved base 12. So twelve hours in the day and 60 (5x12) minutes in the hour. Also 12 months in a year and 360 degrees in a circle.
The French actually tried to implement decimal time after the revolution but reverted back after 6 years or so.